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Play as Marshall Law
Successfully complete one free mode level to unlock Marshall Law from Tekken 5.

Play as Paul Phoenix
Successfully complete challenge mode to unlock Paul Phoenix from Tekken 5.

Play as Bordin
Beat all chapters on free mode with S rank in all missions

Play as Shinkai
Beat all chapters on free mode with A rank in all missions

Play as Golem
Beat chapter 3 on free mode with B or above in all missions.

Play as Ling Fong
Beat chapter 3 on free mode with B or above in all missions.

Play as Napalm99
Beat chapter 2 on free mode with B or above in all missions.

Play as McKinzie
Beat chapter 2 on free mode with B or above in all missions.

Play as Kelly
Beat chapter 1 on free mode with B or above in all missions.

Play as Vera Ross
Beat chapter 1 on free mode with B or above in all missions.

Play as Lilian
Beat chapter 1 on free mode with B or above in all missions.

Challenge Mode
Successfully complete the game to unlock challenge mode.

Free Mode
Successfully complete the game to unlock free mode.

Fighting groups and characters for Multiplayer Mode
Westside Gym, Zaps & KG - Beat mission 30 in story mode
Mushin-Kai & Tin Jiao - Beat mission 99 in story mode
Chris - Beat mission 46 in story mode
Park - Beat mission 60 in story mode
Alex - Beat mission 67 in story mode
Outlaws, Shadow Platoon, Bain & Cooper - Beat mission 70 in story mode